Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to pipeline gas in a gasification process employing partial oxidation and methanation reactions.
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The purpose of coal conversion is the production of alternative fuels, including motor fuels, or the generation of a range of chemicals from coal by process routes, such as gasification, direct and indirect liquefaction, hydropyrolysis, and plasmapyrolysis. The application of these techniques is essential if the large reserves of coal are to be ...
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Ironbased catalysts are promising catalysts in the direct coal liquefaction (DCL) process as they are inexpensive and environmentally friendly. However, most such ironbased catalysts show relatively low activity in coal conversion and oil yield. Common techniques for the synthesis of these catalysts with excellent catalytic performance remain a substantial challenge. We present a simple ...
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Coal liquefaction is very underpowered. It has utility for making blue belts, or if you are low on crude oil. Otherwise it is just worse than advanced oil processing. Liquefaction gives you about 50% petroleum per refinery compared to advanced. Making it comparable to basic oil processing with a giant overhead of cracking and steam production.
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Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
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CCLP Chevron Coal Liquefaction Process CCS Carbon capture and storage CO Carbon monoxide CO 2 Carbon dioxide CPI OPECConsumer Price Index CTL Coaltoliquids DCL Direct coal liquefaction DME Dimethyl ether DOD Department of Defense DOE Department of Energy EDS Exxon Donor Solvent ...
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CO 2 sequestration has been a major concern in application of coal liquefaction technologies because in a typical coal liquefaction process, about 50% carbon in coal is released in the form of CO 2. However, it is important to note that this CO 2 is generated from the gasification or H 2 making unit and is of high purity, more than 98% pure in ...
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The coal hydrogenation reaction process is simply considered as three steps. In the first step, the smaller molecules associated with coal structure units are released as some gases and water in the condition of solvent and heating. In this step, some weaker bonds of the coal structure units are ruptured to form free radicals. The radicals are stabilized by hydrogen atoms from donor solvent ...
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Direct coal liquefaction (DCL) The conversion of coal to liquids via dissolution and/or hydroprocessing, without first gasifying the coal DOE United States Department of Energy FischerTropsch reaction The catalytic conversion of synthesis gas to primarily hydrocarbons, the discovery being credited to Franz Fischer and Hans Tropsch
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In terms of the energy consumption data, the emission factors of SO 2, NO 2 and dust in coal mining and processing and coal transportation can be calculated. Specifically, the emission factors in coal liquefaction were cited from relevant findings with reference to the production status (see Table 8). Dust
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2. Effect of liquefaction processing conditions on the formation and quenching of coal free radicals. Fuel, 1980, 59(4): 227232. Article CAS Google Scholar Petrakis L, Grandy D W. Free radicals in coal and coal conversions. 6. Effects of liquefaction process variables on the insitu observation of free radicals.
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Irdi et al. (1998) deashed and gasified DCLR to improve the economy of the direct coal liquefaction process. DCLR can be used as a raw material for preparing hydrogen for the coal liquefaction reaction process. It can be mixed and cogasified with raw coal at a high temperature . Preparation process. Mixing Process.
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Description: The Solvent Refined Coal liquefaction process referred to as SRCII is a thermal liquefaction process; it is an outgrowth of an earlier Solvent Refined Coal process tested by Gulf Oil in the 1960s [20,21,22,23,24]. The earlier process, known as SRCI, was aimed at boiler fuel production of an ashless lowsulfur solid fuel.
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Coal resources have been used to produce liquid transportation fuels by several process routes, collectively referred to as coal liquefaction or, more generally stated, as Coal to Liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
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Abstract The effect of process conditions on the coprocessing technology of crude oil and coal was investigated. Crude oil/coal matching performance, swelling degree, crude oil/coal slurry viscositytemperature characteristics and process parameters were obtained via the laboratory scale and pilot scale studies. The optimum reaction temperature of the coprocessing was 445~450 oC, the ...
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Coal liquefaction products belong to the new generation of fuel substitutes. However, their composition is different to petroleum fuel specifications: they are mainly composed of naphthenes, aromatics, polycondensed naphthenic and aromatic structures, and heteroatomic compounds (bearing nitrogen or oxygen atoms). Their paraffin content is very low.
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Among them, coal liquefaction residue (CLR) is a waste product in the direct liquefaction process of coal . CLR accounts for 2030 wt.% of the mass of raw coal and is rich in polycyclic aromatic hydrocarbons and polyaromatic hydrocarbons and is a mixture which mainly consist of carbon, ash and sulfur. Therefore, CLR can be used as the ...
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Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
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The first commercially available liquefaction process was the Bergius process, developed in Germany as early as 1911 but brought to commercial scale during World War I. This involves mixing coal in an oil recycled from a previous liquefaction run and then reacting the mixture with hydrogen under high pressures ranging from 200 to 700 atmospheres.
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The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
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During coalification, the chemical structure gradually changes to an aromatized structure, acquiring more stability and compactness as the methyl carbons present in the aliphatic chain changes to aromatic carbons thus reducing the spacing between the aromatic units (Blayden et al. 1944; Hirsch 1954; Cartz and Hirsch 1960; Manoj and Kunjomana 201...
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There appears to be considerable potential for improving the processing and economics of direct coal liquefaction through the development and application of highly dispersed catalysts, where the aims are to promote the process of primary coal dissolution, and produce a solubilized product that can be readily upgraded in a second stage over a supported catalyst.
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Based on the liquefaction process, the global coal to liquid (CTL) market is segmented into direct coal liquefaction and indirect coal liquefaction. Indirect coal liquefaction is the most widely used liquefaction technology. This process produces highvalue and cleanburning fuels. Synthetic fuel produced using this technology can be used in ...
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Abstract. First operated in 1973 to refine a sulfurfree solid fuel from coal, the Electric Power Research Institute's small pilot plant at Wilsonville, Alabama, is now a focal point for research and development in coal liquefaction. The solventrefined coal process (SRC) is largely free of ash and so low in sulfur content that it can be burned ...
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Fuel Processing Technology, 8 (1984) 155168 155 Elsevier Science Publishers, Amsterdam Printed in The Netherlands 7HE CHEMICAL NATURE OF ASPHALTENES FROM SOME COAL LIQUEFACTION PROCESSES COLIN E. SNAPE, WILLIAM R. LADNER National Coal Board, Coal Research Establishment, Stoke Orchard, Cheltenham, Glos.
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•Brown Coal Liquefaction (BCL) Process NEDO •Amoco CC TSL Process •Supercritical Gas Extraction (SGE) Process British Coal •MITI Mark I and Mark II CoProcessing •Cherry P Process Osaka Gas Co. •Solvolysis CoProcessing Mitsubishi •Mobil CoProcessing
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