Overall typical composition of a bauxite residue is given in Table 2 and based on the process conditions and region, the bauxite residue composition is tabulated as Table 3 and 4, respectively. Next to the major elements like Fe, Al, Si, Ca, and Na, there are also valuable minor elements such as Ga, V, Zr, and rare earth elements (Evans, 2016).
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Caption: In a demonstration of the basic chemical reactions used in the new process, electrolysis takes place in neutral water. Dyes show how acid (pink) and base (purple) are produced at the positive and negative electrodes. A variation of this process can be used to convert calcium carbonate (CaCO3) into calcium hydroxide (Ca(OH)2), which can then be used to make Portland cement without ...
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Bayer process, bauxite is mixed with caustic soda, or sodium hydroxide, and heated under pressure. ... The lime slaker is used to prepare lime slurry which is pumped to the digestion unit Area 04 to improve boehmite extraction. Burnt (calcined) lime, which is produced externally, is stored on site in a large ...
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Therefore, lime (CaO) and limestone (CaCO 3) are used, as a source of calcium, to harvest cementing calcining RM alone, reactive aluminium phases begin to form at °C. However, at °C, they turn into crystalline corundum (Al 2 O 3 ), a more stable and less reactive phase.
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In Bayer process, low temperature treatment of bauxite generally applicable to gibbsite in the presence of a significant amount of boehmite (>3%), requires a temperature increase and the addition of an additive to improve the leaching conditions. This research is based on improvement of low temperature leaching conditions 108 °C and the addition of lime during the attack of some types of ...
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A process that involves treatment of ore with lime and soda is used in China and Russia. The Bayer process involves four steps: digestion, clarification, precipitation, and calcination. In the first step, bauxite is ground, slurried with a solution of caustic soda ( sodium hydroxide ), and pumped into large pressure tanks called digesters ...
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Abstract The recovery of major components of bauxite residue by carbothermic reduction at °C and subsequent slag leaching in a Na3CO3(aq) solution is studied. Iron recovers primarily to pigiron and lime is added to tune the calcium aluminate slags towards the highly leachable mayenite phase. The concentration of aluminum in the leachate correlates well with the occurrence of ...
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The effect of lime on gibbsite bauxite digestion is different from its effect on diaspore bauxite due to its different composition and digestion properties [15, 16]. In one report, gibbsite bauxite was digested by adding 1% lime at 145 °C, achieving a better digestion efficiency of %. However, excessive lime addition will lead to excess ...
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An improved lime sinter process based on the drysintering is proposed by adding Na 2 Ocontaining compounds to decrease CaO addition and increase alumina leaching property. The molar ratios of CaO to Al 2 O 3 and Na 2 O to Al 2 O 3 are and, respectively.
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Although lime is extensively used when processing diasporic bauxites, the studies on boehmitic bauxites and the overall effects on the process are limited. In this paper, lime impact was investigated at all stages of the Bayer process including the effect on alumina quality, energy and raw material consumptions.
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Most authors' studies have focused on the pyrometallurgical process, especially in the smeltingreduction process for treating lowgrade bauxite. Sellaeg et al. [74] processed the gibbsitic bauxite mixed with lime and coke via the Pedersen process at 1600 ℃ for 60 min. The separation of pig iron and calciumaluminate slag could be achieved ...
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The Bayer process: How alumina is produced from bauxite. The Bayer process is carried out in four steps. First, after the bauxite is crushed, washed and dried, it is dissolved with caustic soda at high temperatures. Next, the mixture is filtered to remove the impurities, called "red mud," which is properly discarded. The remaining alumina ...
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Perovskite 1. Introduction Lime is often considered as a panacea in the Bayer process. Its uses are so widespread that there is virtually no unit operation where it does not find an application. Table 1 gives an overview of the main uses of lime in the Bayer process, including low temperature applications (not all applications are given).
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The lime used was industrialgrade lime, and the digestion liquid was prepared by industrial sodium aluminate solution and analyticalgrade sodium ... The review can advance the current technology on the comprehensive utilization of gibbsitic bauxite, especially process discharge reduction approaches and largescale abatement ways for red mud. ...
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Bayer process and sodalime sintering process are elaborated and compared. As a hybrid process, bauxite residue undergoes a reductive smelting process with lime addition in an electric arc furnace in order to generate aluminaenriched slag. This slag is subsequently treated with high
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Bauxite residue (BR) is generated as a byproduct of the Bayer process. Approximately tons of BR is generated per ton of alumina production but the quantity of bauxite residue depends upon on the quality of the processed bauxite ore and the processing parameter (Primary Aluminium Production).The annual generation of BR in 2019 alone was estimated as 175 million tons (Archambo and Kawatra ...
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The mechanochemical processing of bauxite with lime has been investigated. The milling of bauxite and lime mixtures in an attritor mill resulted in the formation of an iron rich hydrogarnet phase in bauxite/lime slurries containing greater than 9% CaO. ... The role of lime in the Bayer process with less lime is to eliminate the harmful effect ...
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Following soda and carbon additions, the addition of lime into the sintering process of 20 g CaO to 100 g bauxite residue (80% excess to stoichiometric requirements to form Ca 2 SiO 4) is necessary to investigate the consumption of free and bound silica in desilication products, relying on higher thermodynamic affinity with calcium.
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Apart from recovering iron, Liu et al. (2012) employed a sodalime roasting process prior to leaching and magnetic separation of the fine red mud (<75 μm) aiming to develop an economicallyfeasible zero waste utilization process. The sodalime roasting facilitates the formation of sodium aluminosilicate which can then be recovered by leaching.
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Introduction Due to its economics, the Bayer process is still the preferred and most used process globally for producing alumina. Bauxite is the main feedstock of Bayer process. Progressive bauxite quality deterioration is one of the main challenges to the alumina industry.
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Based on lime sintering method, a novel process of alumina production from lowgrade bauxite containing sulfur or fly ash is carried out in this paper. The phase of alumina transforms from 12CaO·7Al 2 O 3 (C 12 A 7) to 4CaO·3Al 2 O 3 ·SO 3 (C 4 A 3 S), whose alumina leaching property is better, through decreasing sinter temperature and time ...
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Therefore, the optimum lime addition in the digestion process of gibbsiteboehmite bauxite should be determined by tests. Mineral Composition Changes During Digestion The mineral compositions in the bauxite residues at 240 ℃ for different digestion times are shown in Fig. 5 .
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Lime addition in the Bayer process enhances the phase transformation rate of goethite and the digestion performance of alumina in highiron bauxite (Chen and Peng, 1998; Peter, 2017). However, there is no report on the promotion scale, especially for the highcalcium medium system.
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The production of alumina (Al2O3) from bauxite via the Bayer process is underpinned by the use of lime in a variety of process reactions. One of the most important is the causticisation of...
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In the lime sinter process the additive is a calcium salt (usually calcite — ... Based on the stability field of silica gel formation, a stepwise acid leaching process for bauxite residue is proposed to facilitate downstream processing of the critical metals. Extraction of scandium from bauxite residue by highpressure leaching in sulfuric ...
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